Jota was a 65th minute substitute for his nation in Frankfurt though the game ended goalless after 90 minutes in what was a competitive contest.
In the extra-time that followed, Liverpool’s No.20 played a crucial role in earning his side a penalty, producing a driving run into the area before being brought down.
Cristiano Ronaldo, however, saw his resulting spot kick saved by goalkeeper Jan Oblak, which meant the tie required a penalty shootout after finishing 0-0.
However, Portugal proceeded to win 3-0 in penalties, with Slovenia’s three attempts saved by goalkeeper Diogo Costa, earning his nation’s advancement.
In this match, Liverpool star had 10/14 Accurate passes, 1 Chances created, 25 Touches, 1/3 Successful dribbles, 3 Passes into final third, 4 Recoveries, 6/12 Duels won
Konate was not on the field when France defeated Belgium 1-0 earlier in the day to advance to the round of eight.
Five minutes from time, an own goal by Jan Vertonghen ended the match in Dusseldorf. Portugal and France will now play on Friday night (8 p.m. BST kickoff) to get to the semi-finals.